PAD PRINTING INK

Boston Industrial Solutions, Inc., has the best pad printing ink lines for printing any application. Our silicone, UV ink, and solvent-based pad printing inks are safe and fade-resistant. Furthermore, we rigorously test these inks to exceed demanding industry standards for performance, adhesion, and compliance. These pad printing inks are excellent for printing different types of applications, including promotional, apparel, consumer electronics, drinkware, sporting goods, silicone rubber, cosmetic packaging, toys, and more.

The Natron® pad printing inks portfolio has medical-grade, high-abrasion, chemical-resistance, dishwasher-safe, and high-density inks. Additionally, we offer in-house custom color matching and ink mixing services. Other ink services that we offer include ink adhesion testing, pad printing training, and custom ink formulation. All these services are available for inkjet, pad printing, and screen-printing inks.

Learn more about the Natron® pad printing inks, how to choose the best ink for your application, and more.

all about pad printing ink

WHAT IS PAD PRINTING INK?

Pad printing ink is a special type of “paint” formulated for application using a pad printing machine to a substrate as a thin ink film (print) that dries quickly. Ink manufacturers combine solvents and solid matter to create the ink. The solid matter includes binders, resins, additives, catalysts, photo initiators, and pigments. The specific formulation of pad printing ink will vary depending on the application, substrate, compliance, and environmental considerations.

The pad printing process is an indirect printing process where a silicone pad transfers a thin film of ink as a 2D image from an engraved plate (cliché) onto a 3D object.

The formula for making pad printing ink is: (solids + solvent = pad printing ink). Where solid matter = binders + resins + other additives. The type and ratio of these components will vary depending on the type of ink.

what is pad printing ink
pad printing ink types

PAD PRINTING INK TYPES

There are several types of ink for pad printing. These are solvent-based ink, UV-curable ink, silicone ink, and water-based ink. Many industries widely use solvent-based inks, which are the most common.

Furthermore, there are two types of pad printing inks: one-component inks and two-component inks.

  • 1-component inks require only a solvent. During printing, the printer adds the solvent as a percentage of the ink weight.
  • 2-component inks require an ink hardener (crosslinker) and a solvent to reduce their viscosity. Depending on the ink series, the ratio is 10:1 (10 parts of the ink to 1 part of the hardener). In other words, the harder is generally 10% of the ink’s weight.

Lastly, pad printing inks are further classified based on the substrates they adhere to. E.g., ink for metals, plastics, glass, silicone, cotton, etc.

Boston Industrial Solutions, Inc., manufactures and provides pad printing ink for almost all possible substrates and applications. Examples of pad printing applications include medical devices, cosmetic packaging, automotive parts, promotional items, toys, sporting goods, appliances, consumer electronics, and more. We will cover solvent-based inks and silicone inks in detail below.

SOLVENT-BASED PAD PRINTING INK

Solvent-based pad printing ink is the most common type of ink used in the pad printing process. These inks use solvent as the base and carrier of the ink. The solvent allows the ink to easily print, spread, and transfer during the pad printing process. Because these inks use solvents, they have a volatile organic compound (VOC) component that varies from one ink to another. After printing, the solvent evaporates, leaving the pigment, resin, and binders, also known as the solids, on the substrate.

silicone ink type
chemical components

THE CHEMICAL COMPONENTS OF PAD PRINTING INK

The chemical components of pad printing ink vary depending on the specific ink formulation and the ink’s intended use. The most important components used to make pad printing ink include binders, resins, solvents (thinners), and pigments (colorants).

In this section, we will examine each of the parts that make up pad printing ink in detail.

SOLVENT BASE

Generally, the solvent (thinner) is typically 10–65% of the ink composition. The solvent in pad printing ink serves several purposes. Pigment (color dispersion) is one of the critical roles of solvent during ink formulation. Solvents evenly suspend the pigments within the ink.

Maintaining the ink viscosity (thickness of the ink) is another important function of the solvent base.

The solvent also plays a critical role in drying and curing the ink. The quick-drying feature is important for maintaining the quality of the print. This helps prevent the ink from smudging. Except for UV inks and silicone inks, all our solvent-based pad printing inks are dry to touch in seconds to minutes after printing. This is part of the reason that it is possible to print wet on wet or a 4-color process with pad printing or screen-printing machines.

The bonding of the ink with the substrate is another function of the solvent base. The solvent helps with the ink bonding with the base material.

Lastly, different substrates have different surface and chemical properties. The choice of solvent in pad printing ink manufacturing is critical to matching the different substrates. Solvents make it possible for one ink to print effectively across multiple substrates.

printing ink solvent base
binders and resins

BINDERS AND RESINS

Both binders and resins play a critical role in pad printing ink formulation. These two components are different, although many ink suppliers use these terms interchangeably. Let’s explore the differences between resins and binders.

Binders constitute 15 to 50% of the composition of the ink. Binders wet the pigment, which facilitates the dispersion of its particles. As a result, binders hold the pigments together, hence creating a consistent and uniform layer of ink on the printed surface. Examples of polymers include acrylics, vinyl, polyurethane, etc. These materials form the adhesion and flexibility properties of the ink. Binders contribute to the ink’s resistance to weather elements, abrasion, moisture, and chemicals.

Resins contribute to the ink’s durability and adhesion, just like binders. Also, they act as a protective barrier and add to the finish (gloss or matte finish) characteristics of the printed image. Most people confuse binders and resins because they have similar polymers.

Lastly, binders and resins act as the adhesive that determines the printing properties of the ink as well as the way it bonds with the substrate.

PIGMENTS (COLORANT SUBSTANCES)

Pigments (colorant substances) constitute 5–30% of ink. We triple-mill the pigments to achieve very fine particles. Next, we disperse these finely milled solid substances in the binder.

Color and opacity are the primary functions of pigments in pad printing ink formulation. Color is the desired hue (shade), whether it’s a standard color, metallic shade, process color, neon (fluorescent) color, or a custom color. Opacity refers to the ink’s transparent characteristics. High-opaque ink ensures that the printed image completely covers and conceals (hides) the underlying substrate, maintaining the ink’s color integrity.

Other functions of pigments include:

  • Maintaining color fastness—the ability to resist fading or changing color when exposed to UV light. At Boston Industrial Solutions, Inc., we use only fade-resistant pigments to formulate the Natron® pad printing ink line.
  • Color consistency is critical when printing on long-term or repeat jobs. During ink formulation, we use special tools to make sure that each color shade is the same from one batch to the next. This assures our customers that they can create custom colors that match our standard colors every time. In addition, our customer is confident that during a large-scale production run, the colors they use will be the same from one batch to the next.
  • Versatility allows for diverse design possibilities and customization to meet specific customer print requirements. Look at our color cards to see the available high-opacity, intermixable standard colors. All our color shades within each series are intermixable to create new shades.
sustainable ink pigments and colorants
what is silicone ink

WHAT IS SILICONE INK?

Silicone ink is a type of screen and pad printing ink that consists of silicone polymers and silicone ink concentrates (pigments) for printing on silicone rubber applications. Additionally, these inks are 2-component inks; for this ink to function, a catalyst (platinum-based) and a thinner (solvent) are required. Silicone inks require heat to dry and cure. However, it is possible to print on other materials, such as glass and metal, using our Citrine® silicone primers.

Lastly, once cured, silicone ink is the only type of print that can stretch, bend, and move with silicone, as well as withstand high temperatures. Once fully cured, silicone ink will hold up to anything silicone can.

CHARACTERISTICS FOR INK FOR PAD PRINTING

Now that you understand the various components of pad printing ink, next we will review the ink’s characteristics. In pad printing, there is no one ink that prints and adheres to all substrates. The different resins, binders, etc. result in creating inks that have different qualities. However, the different inks share common characteristics. These common characteristics are ink durability, adhesion, drying speed, color range, and opacity.

CHARACTERISTICS FOR INK FOR PAD PRINTING
ink data sheets

INK DATA SHEETS

There are several important documents to review to ensure that the pad printing process is carried out safely and in compliance with relevant standards. These datasheets include safety data sheets, technical data sheets, standard operating procedures, etc. We will review the importance of technical data sheets (TDS).

As discussed, pad printing uses one- or two-component solvent-based ink, UV ink, or silicone-based ink. Different inks use different additives and adhere to different substrates. For this reason, it is important to consult the technical data sheet for each ink to determine what ink is suitable for your printing application. A technical data sheet is a specification sheet for a product. It summarizes the technical characteristics of the product and gives the user a full understanding of what and how to use a specific product. Therefore, it is important to review the TDS for each ink before using it.

In a technical data sheet, you will learn:

  • Which pre-treatment methods are required? E.g., PP primer, UV adhesion promoter, flame treatment, corona treatment, etc.
  • Printing and storage parameters, such as temperature and humidity conditions,
  • The appropriate hardeners and solvents to use with a specific ink line are:
  • The duration of post-treatment and cure for a specific ink can vary.
  • What substrate is a particular ink suitable for? For example, EK series ink will adhere to silicone; however, the MG series will bond well to plastic, metal, paper, wood, and glass surfaces.

CONSIDERATIONS WHEN CHOOSING AN INK

There are various factors to consider when choosing the best pad printing ink for your application. Here are the most important factors to consider when choosing ink for your printing application:

  • Substrate: This is the material you will print on. What is the composition of the material?
  • Adhesion and resistance requirements: do you need the ink to be resistant to abrasion, rub, tape, chemicals, and weather elements?
  • Ink coverage power: some inks are transparent, so you need to double print to achieve excellent opacity. For example, most ink mixing colors are transparent compared to standard high-opacity colors.
  • Finish (gloss or matte finish): It is important to determine the type of finish that you need. Do you want a matte finish or a glossy finish?
  • Light resistance (light fastness) is a property of an ink pigment’s resistance to fading when exposed to light.
  • The drying speed of the ink is also critical. However, you can easily control this with solvents. Some inks will dry faster than others.
  • Specialized applications: Specific applications, such as medical devices and silicone, require specialized pad printing inks.
considerations when choosing an ink, including ink for printing silicone substrate
ink additives

INK ADDITIVES

Pad printing additives are substances added to the inks to enhance various characteristics of the ink properties, such as adhesion, drying time, viscosity, and flexibility. Some common types of additives include thinners (solvents), retarders, thickeners, hardeners, adhesion promoters, anti-static paste, matting agents, anti-skinning agents, and flow agents.

Let us review two of the most common types of pad print ink additives: hardener and thinner.

  • Printing ink solvents modify the ink’s viscosity, adhesion, and drying speed. There are different types of solvents, each with a unique evaporation speed. Furthermore, different solvents work with specific inks. E.g., TRM thinner for silicone works best with the SE Series silicone ink. On the other hand, TMG solvent works with MG, MGX, BX, and several other ink series. Please note that the choice of solvent should satisfy the printing project requirements. Additionally, the solvent should work with the ink series that best suits your substrate.
  • Pad printing hardener, known as catalyst or ink crosslinker, enhances the ink’s durability and mechanical strength and crosslinks the ink with the substrate. Once cured, the hardener undergoes a chemical reaction (crosslinking), which forms a three-dimensional structure. These structures increase the ink’s hardness and resistance to chemicals, wear, abrasion, flexibility, and scratching. Hardeners are specially formulated to work with a specific ink series, like solvents. Different inks and applications require different ink-to-hardener ratios. One-component inks do not require hardeners. Therefore, when using an ink, e.g., ST Series, you do not need to add a hardener at all. On the other hand, 2-component inks require a hardener. The ratios range from 5 to 35% of the ink weight.

HOW LONG DOES IT TAKE TO DRY

Different pad printing inks dry at different speeds. For solvent-based inks, the printed ink film takes about 24 hours to dry and about 76 hours to achieve full cure. On the other hand, UV inks dry instantly on exposure to UV light at 395nm. UV inks take about 24 hours to achieve full cure. While silicone inks will eventually air dry, heat is required to speed up drying time.

The amount of hardener (catalyst) used affects the rate at which the printed image dries. Moreover, the use of faster-evaporating solvents will increase the rate at which the ink film dries.

Consider using heat tunnels to speed up the drying process of the ink. Except for silicone, after heating the substrate, other inks still require a 24-hour period to achieve full cure. Silicone inks cure immediately after the heated silicone product cools down.

Lastly, on average, it takes about 25 seconds for most solvent-based pad printing inks to achieve “dry-to-touch” status.

pad print tooling fixtures
pad print tooling fixtures

TYPES OF APPLICATIONS

At Boston Industrial Solutions, Inc., we offer inks to many industries and for printing on many types of materials and applications. Some of the industries that use our inks include:

  • Inks for making medical devices.
  • Food packaging: Our inks are food-contact-safe and are compliant with Title 21 of the U.S. Code of Federal Regulations (21 CFR), which exclude polluting components.
  • Toys: The Natron® series inks are compliant and do not contain 19 forbidden elements.
  • Automotive industries rely on our inks for printing automotive parts.
  • Consumer products and electronic devices
  • Aerospace and space exploration applications, etc.

Every ink that Boston Industrial Solutions, Inc. manufactures and supplies conforms to the most stringent worldwide standards, such as EuPIA, GADSL, RoHS, EN 71/3, REACH, USP Class VI, cGMP, GAMP5, and FDA.

IS IT POSSIBLE TO PRINT ALL MATERIALS WITH PAD PRINTING INKS?

The scientific and manufacturing industries are always coming up with new materials. For this reason, it might not be possible to have ink to print on all substrates. However, for the most challenging applications, with the combination of adhesion promoters, it is possible to print on almost all materials. Boston Industrial Solutions, Inc. offers different types of inks for printing on almost any kind of material that you can think of, such as:

  • Silicone rubber,
  • Silicone-coated and impregnated fabrics.
  • Acrylonitrile butadiene styrene (ABS)
  • Acrylonitrile styrene acrylate (ASA)
  • Aluminum
  • Cellulose acetate
  • Ceramics
  • Chromium-plated surfaces
  • Coated surfaces
  • Cotton
  • Duroplastics (phenolic and melamine resins, glass-fiber-reinforced polyester, and epoxy resins)
  • Glass
  • Gold-plated surfaces
  • Leather
  • Metals
  • Nickel-plated surfaces
  • Rhodium-coated surfaces
  • Paper
  • Plasticized PVC
  • PMMA (acrylic glass)
  • Polyacetal (POM, with flame-drying)
  • Polyamide (PA)
  • Polycarbonate (PC)
  • Polyester (PES)
  • Polymer blends like PC and ABS
  • Polystyrene (PS)
  • Polyurethane (PU)
  • Pre-treated polyolefines, i.e., polypropylene (PP), polyethylene (HD-PE, LD-PE),
  • Rigid PVC
  • Rubber (EPDM)
  • Rubber (Nitrile)
  • Rubber (EVA)
  • Silicone rubber
  • Styrene acrylonitrile resin (SAN)
  • Synthetic leather
  • Thermoplastic elastomers (TPE, TPU, TPS, soft-touch coatings)
  • Wood
6-color pad printing machine
printing ink color matching services

INK COLOR MATCHING SERVICES

Ink mixing is an interchangeable term for ink color matching. Over the years, Boston Industrial Solutions, Inc., has developed a large library of colors. We store these colors in our color-matching system. These colors are available for all our pad printing ink ranges.

If a color is not available, following the RAL, PMS, or HEX system, we can formulate any color that you can dream of. We use advanced tools such as spectrophotometers to accurately calculate and match the ratios needed for a perfect color match. We match inks to perfectly print nearly any shade on any printable substrate background, dark or light.

INK ADHESION TESTING

Adhesion testing is an important part of the development and quality control of pad printing. Adhesion testing ensures that printed images meet customer-required standards for durability and longevity. Additionally, it helps identify potential problems in pre-production.

At Boston Industrial Solutions, Inc., we offer ink adhesion testing following the ASTM industry standards.

adhesion testing method
Low coefficient of silicone coating

COMPLIANCE AND CERTIFICATIONS

There are very many industries that use pad printing inks for marking, printing, and decorating products. Many people use these products daily. As a result, it is very important that inks comply with various standards.

The reasons for compliance include product safety, consumer protection, environmental impact, worker health and safety, legal requirements, global markets, quality, supply chain management, and ethical considerations.

The most common compliance and certifications for pad printing inks include RSL, CPSIA, EuPIA, GADSL, RoHS, EN 71/3, REACH, USP Class VI, cGMP, GAMP5, and FDA.

All our printing inks do not contain heavy metals (lead, cadmium, mercury) or phthalates. In addition, some of our inks, such as the SE-F, MG, and BX series, are Class IV certified. This means that these inks meet strict medical safety standards.

For pad printing on textiles, important certification includes Eco Passport by Oeko-Tex®. This compliance testing checks for chemicals, colorants, and auxiliaries used to manufacture textiles. It checks inks for human skin contact. The ST Series ink for tagless printing on apparel ensures no exposure to toxic chemicals when prints come into contact with human skin. Since these tags are touching skin for prolonged periods of time daily, it is essential that there be no exposure to toxic chemicals.

OTHER CERTIFICATIONS

Specifications are requirements by the end user that pad printing inks have specific characteristics and meet certain standards. For example, Military (MIL-Spec)/Aerospace Qualified Ink-Military spec to MIL-I-43553 and AA56032. When properly applied and cured, the ink has excellent adhesion to metal, glass, and hard plastics. The ink is resistant to acids, alkalies, solvents, salt spray, and thermal shock. The Natron MG Series ink for glass, metals, ceramics, and hard plastics meets military specifications for MIL-I-43553 and AA56032. This printing ink is a permanent, two-component, epoxy-based printing ink. Use the i-240x hardener, which cures at elevated and/or room temperatures. For room-temperature curing, perform adhesion testing 18–36 hours after printing. This waiting time enables the ink to cross-link to the substrate. In some cases, the printed product can take up to 6 days to achieve full cure.

printing ink certifications
troubleshooting

TROUBLE SHOOTING: PAD PRINT INK RELATED PROBLEMS

Like any other printing method, there are certain pad printing ink-related problems that may affect the quality of the prints. It is therefore important to identify and address these issues to achieve consistent printing results. Here are some common ink problems during pad printing:

Poor ink adhesion, ink bleeding (leaking from the cup), ink smearing, ink drying too quickly, ink contamination, ink not transferring properly, ghosting, and ink curing issues. Visit our support hub for more information.

CONCERNS AND FUTURE DEVELOPMENTS

As we conclude, let’s review concerns and new developments in pad printing ink. The current concerns include:

  • Environment impact
  • Regulatory compliance
  • Substrate compatibility
  • Durability and resistance properties of the material

Most of the new developments in the pad printing industry are sustainability-driven. The new areas of development include:

  • UV-curable inks reduce drying times, lower VOCs, and energy consumption.
  • Migration from pad printing to UV printers.
how to improve UV print durability
certified glass ink

OUR PAD PRINTING INK LINE

For more information on our pad printing inks, check out the Pad Printing Ink Overview on our blog.